{"id":14030,"date":"2025-04-25T01:57:33","date_gmt":"2025-04-25T01:57:33","guid":{"rendered":"https:\/\/scienceweb.clemson.edu\/uacl-new\/?p=14030"},"modified":"2025-11-06T02:12:42","modified_gmt":"2025-11-06T02:12:42","slug":"reu-project-04","status":"publish","type":"post","link":"https:\/\/scienceweb.clemson.edu\/uacl\/reu-project-04\/","title":{"rendered":"Light emitting materials based on chiral DES"},"content":{"rendered":"\t\t<div data-elementor-type=\"wp-post\" data-elementor-id=\"14030\" class=\"elementor elementor-14030\">\n\t\t\t\t<div class=\"elementor-element elementor-element-d82a6ab e-flex e-con-boxed mk-enable-fade-animation-none mk-sticky-column-false mk-sticky-column-disable-tablet e-con e-parent\" data-id=\"d82a6ab\" data-element_type=\"container\" data-e-type=\"container\" data-settings=\"{&quot;mk-animation-effect&quot;:&quot;none&quot;,&quot;mk_ext_is_sticky&quot;:&quot;false&quot;}\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t<div class=\"elementor-element elementor-element-2ce233f e-con-full e-flex mk-enable-fade-animation-none mk-sticky-column-false mk-sticky-column-disable-tablet e-con e-child\" data-id=\"2ce233f\" data-element_type=\"container\" data-e-type=\"container\" data-settings=\"{&quot;mk-animation-effect&quot;:&quot;none&quot;,&quot;mk_ext_is_sticky&quot;:&quot;false&quot;}\">\n\t\t\t\t<div class=\"elementor-element elementor-element-c7ed443 mk-enable-fade-animation-none elementor-widget elementor-widget-theme-post-featured-image elementor-widget-image\" data-id=\"c7ed443\" data-element_type=\"widget\" data-e-type=\"widget\" data-settings=\"{&quot;mk-animation-effect&quot;:&quot;none&quot;,&quot;mk_ext_is_infinite&quot;:&quot;false&quot;,&quot;mk_ext_is_scrollme&quot;:&quot;false&quot;}\" data-widget_type=\"theme-post-featured-image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<img fetchpriority=\"high\" decoding=\"async\" width=\"750\" height=\"765\" src=\"https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/REU_project_04.png\" class=\"attachment-large size-large wp-image-14103\" alt=\"REU project 04\" srcset=\"https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/REU_project_04.png 750w, https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/REU_project_04-294x300.png 294w\" sizes=\"(max-width: 750px) 100vw, 750px\" \/>\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-94b18d8 e-con-full e-flex mk-enable-fade-animation-none mk-sticky-column-false mk-sticky-column-disable-tablet e-con e-child\" data-id=\"94b18d8\" data-element_type=\"container\" data-e-type=\"container\" data-settings=\"{&quot;mk-animation-effect&quot;:&quot;none&quot;,&quot;mk_ext_is_sticky&quot;:&quot;false&quot;}\">\n\t\t\t\t<div class=\"elementor-element elementor-element-a6b7dba mk-enable-fade-animation-none elementor-widget elementor-widget-text-editor\" data-id=\"a6b7dba\" data-element_type=\"widget\" data-e-type=\"widget\" data-settings=\"{&quot;mk-animation-effect&quot;:&quot;none&quot;,&quot;mk_ext_is_infinite&quot;:&quot;false&quot;,&quot;mk_ext_is_scrollme&quot;:&quot;false&quot;}\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p><span style=\"color: #000000\">This research aims to develop and characterize circularly polarized light-emitting materials based on chiral DES that are solvents for luminescent lanthanide complexes. Recent work has demonstrated that chiral DES (incorporating at least one chiral component) can induce circularly polarized luminescence (CPL) from luminescent lanthanide (europium and terbium) complexes. These results evidenced that both chiral and achiral components play an essential role in influencing the induced CPL.\u00a0Aiming to further this work, participants in this research project will engage in various activities, ranging from improving a current database of chiral DES (already containing ~400 binary entries) to exploring ternary chiral DES mixtures, where the third component will be used to improve the solubility and control CPL from the lanthanide solutes. Participants will also be involved with the characterization of the DES\u2019 ability to induce photoluminescent CPL from 1) non-covalent interactions with a racemic mixture of luminescent lanthanide complexes and 2) through a coordination interaction between the chiral DES solvent and luminescent lanthanide complexes. By the end of the summer, participants will also get the chance to build (and test) CP-OLEDs (circularly-polarized organic light-emitting diodes) incorporating their own chiral DES + lanthanide complexes. In addition to the training linked to the characterization of the DES (melting point, density, and CPL spectra), participants will also be introduced to basic molecular dynamics simulations and electronic structure calculations, to explain the CPL induced by the chiral DES.<\/span><\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-9e30930 e-flex e-con-boxed mk-enable-fade-animation-none mk-sticky-column-false mk-sticky-column-disable-tablet e-con e-parent\" data-id=\"9e30930\" data-element_type=\"container\" data-e-type=\"container\" data-settings=\"{&quot;mk-animation-effect&quot;:&quot;none&quot;,&quot;mk_ext_is_sticky&quot;:&quot;false&quot;}\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t\t\t<div class=\"elementor-element elementor-element-52499e8 mk-enable-fade-animation-none elementor-widget elementor-widget-spacer\" data-id=\"52499e8\" data-element_type=\"widget\" data-e-type=\"widget\" data-settings=\"{&quot;mk-animation-effect&quot;:&quot;none&quot;,&quot;mk_ext_is_infinite&quot;:&quot;false&quot;,&quot;mk_ext_is_scrollme&quot;:&quot;false&quot;}\" data-widget_type=\"spacer.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-spacer\">\n\t\t\t<div class=\"elementor-spacer-inner\"><\/div>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-688a9f6 e-flex e-con-boxed mk-enable-fade-animation-none mk-sticky-column-false mk-sticky-column-disable-tablet e-con e-parent\" data-id=\"688a9f6\" data-element_type=\"container\" data-e-type=\"container\" data-settings=\"{&quot;mk-animation-effect&quot;:&quot;none&quot;,&quot;mk_ext_is_sticky&quot;:&quot;false&quot;}\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t<div class=\"elementor-element elementor-element-f8f2a1f e-con-full e-flex mk-enable-fade-animation-none mk-sticky-column-false mk-sticky-column-disable-tablet e-con e-child\" data-id=\"f8f2a1f\" data-element_type=\"container\" data-e-type=\"container\" data-settings=\"{&quot;mk-animation-effect&quot;:&quot;none&quot;,&quot;mk_ext_is_sticky&quot;:&quot;false&quot;}\">\n\t\t\t\t<div class=\"elementor-element elementor-element-65a1d1a mk-enable-fade-animation-none elementor-widget elementor-widget-image\" data-id=\"65a1d1a\" data-element_type=\"widget\" data-e-type=\"widget\" data-settings=\"{&quot;mk-animation-effect&quot;:&quot;none&quot;,&quot;mk_ext_is_infinite&quot;:&quot;false&quot;,&quot;mk_ext_is_scrollme&quot;:&quot;false&quot;}\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<img decoding=\"async\" width=\"200\" height=\"200\" data-src=\"https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/todd_hopkins.jpeg\" class=\"attachment-large size-large wp-image-14734 lazyload\" alt=\"todd hopkins\" data-srcset=\"https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/todd_hopkins.jpeg 200w, https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/todd_hopkins-150x150.jpeg 150w, https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/todd_hopkins-105x105.jpeg 105w\" data-sizes=\"(max-width: 200px) 100vw, 200px\" src=\"data:image\/svg+xml;base64,PHN2ZyB3aWR0aD0iMSIgaGVpZ2h0PSIxIiB4bWxucz0iaHR0cDovL3d3dy53My5vcmcvMjAwMC9zdmciPjwvc3ZnPg==\" style=\"--smush-placeholder-width: 200px; --smush-placeholder-aspect-ratio: 200\/200;\" \/>\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-18f1908 e-con-full e-flex mk-enable-fade-animation-none mk-sticky-column-false mk-sticky-column-disable-tablet e-con e-child\" data-id=\"18f1908\" data-element_type=\"container\" data-e-type=\"container\" data-settings=\"{&quot;mk-animation-effect&quot;:&quot;none&quot;,&quot;mk_ext_is_sticky&quot;:&quot;false&quot;}\">\n\t\t\t\t<div class=\"elementor-element elementor-element-831dffb mk-enable-fade-animation-none elementor-widget elementor-widget-text-editor\" data-id=\"831dffb\" data-element_type=\"widget\" data-e-type=\"widget\" data-settings=\"{&quot;mk-animation-effect&quot;:&quot;none&quot;,&quot;mk_ext_is_infinite&quot;:&quot;false&quot;,&quot;mk_ext_is_scrollme&quot;:&quot;false&quot;}\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p><span style=\"color: #000000\"><strong>Students working in this project will be mentored by Dr. Todd Hopkins, at Butler University\u00a0<\/strong><\/span><\/p><p><span style=\"color: #000000\"><a style=\"color: #000000\" href=\"https:\/\/www.butler.edu\/arts-sciences\/chemistry-biochemistry\/faculty-staff\/\"><img decoding=\"async\" class=\"size-full wp-image-14115 lazyload\" title=\"icons8 website\" data-src=\"https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/icons8-website.gif\" alt=\"icons8 website\" width=\"50\" height=\"50\" src=\"data:image\/svg+xml;base64,PHN2ZyB3aWR0aD0iMSIgaGVpZ2h0PSIxIiB4bWxucz0iaHR0cDovL3d3dy53My5vcmcvMjAwMC9zdmciPjwvc3ZnPg==\" style=\"--smush-placeholder-width: 50px; --smush-placeholder-aspect-ratio: 50\/50;\" \/><\/a> <\/span><a href=\"https:\/\/scholar.google.com\/citations?user=9lPfou8AAAAJ&amp;hl=en\"><span style=\"color: #000000\"><img decoding=\"async\" class=\"size-full wp-image-14116 lazyload\" title=\"icons8 google scholar 50\" data-src=\"https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/icons8-google-scholar-50.png\" alt=\"icons8 google scholar 50\" width=\"50\" height=\"50\" data-srcset=\"https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/icons8-google-scholar-50.png 50w, https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/elementor\/thumbs\/icons8-google-scholar-50-r53orhp59nh1i1yl0nelevkoz1i2lwo3xev7el2dy6.png 35w\" data-sizes=\"(max-width: 50px) 100vw, 50px\" src=\"data:image\/svg+xml;base64,PHN2ZyB3aWR0aD0iMSIgaGVpZ2h0PSIxIiB4bWxucz0iaHR0cDovL3d3dy53My5vcmcvMjAwMC9zdmciPjwvc3ZnPg==\" style=\"--smush-placeholder-width: 50px; --smush-placeholder-aspect-ratio: 50\/50;\" \/><\/span><\/a><\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"<p>This research aims to develop and characterize circularly polarized light-emitting materials based on chiral DES that are solvents for luminescent lanthanide complexes. Recent work has demonstrated that chiral DES (incorporating at least one chiral component) can induce circularly polarized luminescence (CPL) from luminescent lanthanide (europium and terbium) complexes. These results evidenced that both chiral and achiral components play an essential role in influencing the induced CPL.\u00a0Aiming to further this work, participants in this research project will engage in various activities, ranging from improving a current database of chiral DES (already containing ~400 binary entries) to exploring ternary chiral DES mixtures, [&hellip;]<\/p>\n","protected":false},"author":20,"featured_media":14103,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":"","_links_to":"","_links_to_target":""},"categories":[158],"tags":[],"class_list":["post-14030","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-reu_03_projects"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.6 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Light emitting materials based on chiral DES - Microanalytical Chemistry Lab<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/scienceweb.clemson.edu\/uacl\/reu-project-04\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Light emitting materials based on chiral DES - Microanalytical Chemistry Lab\" \/>\n<meta property=\"og:description\" content=\"This research aims to develop and characterize circularly polarized light-emitting materials based on chiral DES that are solvents for luminescent lanthanide complexes. Recent work has demonstrated that chiral DES (incorporating at least one chiral component) can induce circularly polarized luminescence (CPL) from luminescent lanthanide (europium and terbium) complexes. These results evidenced that both chiral and achiral components play an essential role in influencing the induced CPL.\u00a0Aiming to further this work, participants in this research project will engage in various activities, ranging from improving a current database of chiral DES (already containing ~400 binary entries) to exploring ternary chiral DES mixtures, [&hellip;]\" \/>\n<meta property=\"og:url\" content=\"https:\/\/scienceweb.clemson.edu\/uacl\/reu-project-04\/\" \/>\n<meta property=\"og:site_name\" content=\"Microanalytical Chemistry Lab\" \/>\n<meta property=\"article:published_time\" content=\"2025-04-25T01:57:33+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2025-11-06T02:12:42+00:00\" \/>\n<meta property=\"og:image\" content=\"https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/REU_project_04.png\" \/>\n\t<meta property=\"og:image:width\" content=\"750\" \/>\n\t<meta property=\"og:image:height\" content=\"765\" \/>\n\t<meta property=\"og:image:type\" content=\"image\/png\" \/>\n<meta name=\"author\" content=\"CDG\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:creator\" content=\"@MicroAnalytic11\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"CDG\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"2 minutes\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\\\/\\\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"https:\\\/\\\/scienceweb.clemson.edu\\\/uacl\\\/reu-project-04\\\/#article\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/scienceweb.clemson.edu\\\/uacl\\\/reu-project-04\\\/\"},\"author\":{\"name\":\"CDG\",\"@id\":\"https:\\\/\\\/scienceweb.clemson.edu\\\/uacl\\\/#\\\/schema\\\/person\\\/84db2eae9183261b17b2280646687289\"},\"headline\":\"Light emitting materials based on chiral DES\",\"datePublished\":\"2025-04-25T01:57:33+00:00\",\"dateModified\":\"2025-11-06T02:12:42+00:00\",\"mainEntityOfPage\":{\"@id\":\"https:\\\/\\\/scienceweb.clemson.edu\\\/uacl\\\/reu-project-04\\\/\"},\"wordCount\":250,\"publisher\":{\"@id\":\"https:\\\/\\\/scienceweb.clemson.edu\\\/uacl\\\/#organization\"},\"image\":{\"@id\":\"https:\\\/\\\/scienceweb.clemson.edu\\\/uacl\\\/reu-project-04\\\/#primaryimage\"},\"thumbnailUrl\":\"https:\\\/\\\/scienceweb.clemson.edu\\\/uacl\\\/wp-content\\\/uploads\\\/sites\\\/46\\\/2025\\\/04\\\/REU_project_04.png\",\"articleSection\":[\"REU_03_projects\"],\"inLanguage\":\"en-US\"},{\"@type\":\"WebPage\",\"@id\":\"https:\\\/\\\/scienceweb.clemson.edu\\\/uacl\\\/reu-project-04\\\/\",\"url\":\"https:\\\/\\\/scienceweb.clemson.edu\\\/uacl\\\/reu-project-04\\\/\",\"name\":\"Light emitting materials based on chiral DES - 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Microanalytical Chemistry Lab","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/scienceweb.clemson.edu\/uacl\/reu-project-04\/","og_locale":"en_US","og_type":"article","og_title":"Light emitting materials based on chiral DES - Microanalytical Chemistry Lab","og_description":"This research aims to develop and characterize circularly polarized light-emitting materials based on chiral DES that are solvents for luminescent lanthanide complexes. Recent work has demonstrated that chiral DES (incorporating at least one chiral component) can induce circularly polarized luminescence (CPL) from luminescent lanthanide (europium and terbium) complexes. These results evidenced that both chiral and achiral components play an essential role in influencing the induced CPL.\u00a0Aiming to further this work, participants in this research project will engage in various activities, ranging from improving a current database of chiral DES (already containing ~400 binary entries) to exploring ternary chiral DES mixtures, [&hellip;]","og_url":"https:\/\/scienceweb.clemson.edu\/uacl\/reu-project-04\/","og_site_name":"Microanalytical Chemistry Lab","article_published_time":"2025-04-25T01:57:33+00:00","article_modified_time":"2025-11-06T02:12:42+00:00","og_image":[{"width":750,"height":765,"url":"https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/REU_project_04.png","type":"image\/png"}],"author":"CDG","twitter_card":"summary_large_image","twitter_creator":"@MicroAnalytic11","twitter_misc":{"Written by":"CDG","Est. reading time":"2 minutes"},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"Article","@id":"https:\/\/scienceweb.clemson.edu\/uacl\/reu-project-04\/#article","isPartOf":{"@id":"https:\/\/scienceweb.clemson.edu\/uacl\/reu-project-04\/"},"author":{"name":"CDG","@id":"https:\/\/scienceweb.clemson.edu\/uacl\/#\/schema\/person\/84db2eae9183261b17b2280646687289"},"headline":"Light emitting materials based on chiral DES","datePublished":"2025-04-25T01:57:33+00:00","dateModified":"2025-11-06T02:12:42+00:00","mainEntityOfPage":{"@id":"https:\/\/scienceweb.clemson.edu\/uacl\/reu-project-04\/"},"wordCount":250,"publisher":{"@id":"https:\/\/scienceweb.clemson.edu\/uacl\/#organization"},"image":{"@id":"https:\/\/scienceweb.clemson.edu\/uacl\/reu-project-04\/#primaryimage"},"thumbnailUrl":"https:\/\/scienceweb.clemson.edu\/uacl\/wp-content\/uploads\/sites\/46\/2025\/04\/REU_project_04.png","articleSection":["REU_03_projects"],"inLanguage":"en-US"},{"@type":"WebPage","@id":"https:\/\/scienceweb.clemson.edu\/uacl\/reu-project-04\/","url":"https:\/\/scienceweb.clemson.edu\/uacl\/reu-project-04\/","name":"Light emitting materials based on chiral DES - 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