Publications

From Clemson

(† undergraduate student)

 

14. Enantioselective Deoxygenative Amino-Cyanation of Carboxylic Acids via Ti-Multicatalysis

Gu tierrez, G.; Wilt, A. J.; Muhammad, S.; Girotti, E.†; Rodriguez,D.†; Kim, B.*

Graphic of Enantioselective Deoxygenative Amino-Cyanation of Carboxylic Acids via Ti-Multi-catalysis.

13. Ammonium-Binding Bifunctional Aza-Crown Ether Catalysts for Substrate-Selective Hydroxyl Functionalization

Seilkop, A. G.; Odoh, A. S.; Coradi, N. J.†; Wright, J. I.†; Barroso, J.; Kim, B.*

Graphic of Ammonium-Binding Bifunctional Aza-Crown Ether Catalysts.

12. SuFEx-Enabled Direct Deoxy-Diversification of Alcohols

Graphic of Direct Deoxy-Diversification of Alcohols.

11. Asymmetric Catalysis Mediated by Synthetic Peptides, Version 2.0: Expansion of Scope and Mechanisms

  • Metrano, A. J.; Chinn, A.J.; Shugrue, C. R.; Stone, E.A.; Kim, B.; Miller, S.J.
  • Chem. Rev. 2020, 120, 11479–11615.
Graphic of Asymmetric Catalysis Mediated by Synthetic Peptides.

10. Application of High-Throughput Competition Experiments in the Development of Aspartate Directed Site-Selective Modification of Tyrosine Residues in Peptides

  • Chinn, A.J.; Hwang, J.; Kim, B.; Parish, C. A.; Krska, S. W.; Miller, S.J.
  • J. Org. Chem. 2020, 85, 9424–9433.
Graphic of Aspartate Directed Site-Selective Modification of Tyrosine Residues in Peptides.

Mentored Work

9. A Stereodynamic Redox-Interconversion Network of Vicinal Tertiary and Quaternary Carbon Stereocenters in Hydroquinone-Quinone Hybrid Dihydrobenzofurans

  • Storch, G.; Kim, B.; Mercado, B. Q.; Miller, S.J.
  • Angew. Chem. Int. Ed. 2018, 57, 15107–15111.
Graphic of Vicinal Tertiary and Quaternary Carbon Stereocenters.

8. Hydrogenation Catalyst Generates Cyclic Peptide Stereocenters in Sequence

  • Le, D.N.; Hansen, E.; Khan, H.K.; Kim, B.; Wiest, O.; Dong, V.M.
  • Nat. Chem. 2018, 10, 968–973.
Graphic of Hydrogenation Catalyst Generates Cyclic Peptide Stereocenters in Sequence.

7. Divergent Control of Point and Axial Stereogenicity: Catalytic Enantioselective C−N Bond- Forming Cross-Coupling and Catalyst-Controlled Atroposelective Cyclodehydration

  • Kwon, Y.; Chinn, A.J.; Kim, B.; Miller, S.J.
  • Angew. Chem. Int. Ed. 2018, 57, 6251–6255.
Graphic of Divergent Control of Point and Axial Stereogenicity.

6. Enantioselective Intermolecular C–O Bond Formation in the Desymmetrization of Diarylmethines Employing a Guanidinylated Peptide-Based Catalyst

  • Chinn, A.J.; Kim, B.; Kwon. Y.; Miller, S.J.
  • J. Am. Chem. Soc. 2017, 139, 18107–18114.
Graphic of Enantioselective Intermolecular C–O Bond Formation.

5. Stereodynamic Quinone-Hydroquinone Molecules That Enantiomerize at sp3-Carbon via Redox-Interconversion

  • Kim, B.; Storch, G.; Banerjee, G.; Mercado, B.Q.; Castillo-Lora, J.; Brudvig, G. W.; Mayer, J.M.; Miller, S.J.
  • J. Am. Chem. Soc. 2017, 139, 15239–15244.
Graphic of Stereodynamic Quinone-Hydroquinone Molecules.

4. Distal Stereocontrol Using Guanidinylated Peptides as Multifunctional Ligands: Desymmetrization of Diarylmethanes via Ullmann Cross-Coupling

  • Kim, B.; Chinn, A. J.; Fandrick, D. R.; Senanayake, C. H.; Singer, R. A.; Miller, S. J.
  • J. Am. Chem. Soc. 2016, 138, 7939–7945.
Graphic of Distal Stereocontrol Using Guanidinylated Peptides.

3. Inhibition of Steroid Sulfatase with 4-Substituted Estrone and Estradiol Derivatives

  • Phan, C.M.; Liu, Y.; Kim, B.; Mostafa, Y.; Taylor, S.D.
  • Bioorg. Med. Chem. 2011, 19, 5999–6005.
Graphic of Inhibition of Steroid Sulfatase.

2. Phthalides by Rhodium-Catalyzed Ketone Hydroacylation

  • Phan, D.H.T.; Kim, B.; Dong, V.M.
  • J. Am. Soc. Chem. 2009, 131, 15608–15609.
Graphic of Phthalides by Rhodium-Catalyzed Ketone Hydroacylation.

1. Synthesis of 4-Formyl Estrone Using a Positional Protecting Group and Its Conversion to Other C-4-Substituted Estrogens

  • Liu, Y.; Kim, B.; Taylor, S.D.
  • J. Org. Chem. 2007, 72, 8824–8830.
Graphic of Synthesis of 4-Formyl Estrone.

Address

Clemson University
Department of Chemistry
Hunter Hall, 211 S. Palmetto Blvd
Clemson, SC 29634, USA

Contact

Lab – Hunter Hall 443, 446
Office – Hunter Hall 463
byoungk@clemson.edu
864-656-1666

the kim group clemson paw and buldings